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2011). 5. Metal Organic Frame Work Metal organic frameworks (MOFs) are new micro-porous materials with exceptional high porosity, uniform pore size, well-defined molecular adsorption sites and large surface area (up to 5500m2/g) (Saha and Deng 2010, Saha and Deng 2010). MOFs have two main components: the organic linkers considered as organic secondary building unit, act as struts that bridge metal centres known as inorganic primary building units and act as joints in the resulting MOF architecture.
2006, Zuh et al. 2006, Daou et al. 2007). 2. Chlorides/Porous Media Composite Adsorbents Adding chloride salts to expanded graphite, activated carbon, activated carbon fiber, zeolite and vermiculite is used to enhance these materials adsorptivity. Chloride salts/expandable graphite composite showed enhanced heat and mass transfer performance without expansion during adsorption (Deshmukh and Joshi, 2012). 95 kgref/kgads), but activated carbon performs better than activated carbon fibres in term of not separating from the salt (Ghorrishi et al.
On the other hand, the temperature and quantity of energy required for adsorption influence the energy savings and the range of industries that can benefit from such systems. Therefore they should be equally weighted. 38 A. Rezk, A. Mahmoud et al. Table 7. 17 -34 65 79 -48 100 100 1368 1102 842 217 2258 2258 Adsorption heat kJ/kg 18002000 1800-2000 1200-1400 18302300 2500-2800 3200-4200 Cooling density 2000 W/kg 140-500 W/kg 118159kJ/kg 57 kJ/kg 190W/kg 90150W/kg Adsorption capacity kgref/kgads Refrigerant boiling point ˚C Refrigerant latent heat of vaporization kJ/kg Table 8.